I was working with SCCM Compliance system. I deployed a baseline to clients. I was curious if it was working. I know I can login to the client, bring up Configmgr Control panel and go to the Configurations tab, select the baseline and click Evaluate. Then I thought checked RCT to see if they had a way to kick-off this evaluation. Didn't find any so my idea is to be able to RCT on a system or collection and then start the Configuration Management baselines. Not sure how to deal with picking which baseline to update, so perhaps all of them would suffice?
Remote Software Center - Compliance tab has a list of baselines and each device's compliance. You can reevaluate individual baselines from that tab, too.